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1. Which of the following alcohols would be expected to react fastest with Lucas reagent (via the SN1 mechanism) due to carbocation stability: primary, secondary, or tertiary?
- A. All react at the same rate
- B. Secondary alcohol
- C. Tertiary alcohol
- D. Primary alcohol
Answer: Tertiary alcohol
Explanation: Tertiary alcohol — verified fact for BITSAT Chemistry.
2. In alkyl halides, the carbon-halogen bond is polarised such that the carbon atom carries a partial charge of:
- A. Partial positive (δ+), since halogen is more electronegative
- B. No charge at all; the bond is completely non-polar
- C. Partial negative (δ-)
- D. Full positive charge (+1)
Answer: Partial positive (δ+), since halogen is more electronegative
Explanation: Partial positive (δ+), since halogen is more electronegative — verified fact for BITSAT Chemistry.
3. Which test is commonly used to detect the presence of an aldehyde group using Fehling's solution, based on the colour of the precipitate formed?
- A. Formation of a blue precipitate of Cu(OH)₂ that persists unchanged
- B. Formation of a brick-red precipitate of Cu₂O
- C. Formation of a white precipitate of AgCl
- D. No visible change occurs
Answer: Formation of a brick-red precipitate of Cu₂O
Explanation: Formation of a brick-red precipitate of Cu₂O — verified fact for BITSAT Chemistry.
4. Which functional group isomerism relationship exists between an aldehyde and a ketone with the same molecular formula (e.g., propanal and propanone... note propanone has 3 carbons and propanal has 3 carbons but different connectivity)? More precisely, butanal and butan-2-one share the same molecular formula C₄H₈O — what type of isomerism is this?
- A. Chain isomerism
- B. Geometrical isomerism
- C. Position isomerism
- D. Functional group isomerism
Answer: Functional group isomerism
Explanation: Functional group isomerism — verified fact for BITSAT Chemistry.
5. What is the IUPAC name of the compound CH₃-CH₂-NH₂?
- A. Methanamine
- B. Ethanamide
- C. Ethanol
- D. Ethanamine
Answer: Ethanamine
Explanation: Ethanamine — verified fact for BITSAT Chemistry.
6. Which acid-base theory defines acids and bases strictly in terms of proton (H⁺) donation and acceptance, without reference to electron pairs?
- A. Lewis theory
- B. VSEPR theory
- C. Arrhenius theory only covers bases, not this distinction
- D. Bronsted-Lowry theory
Answer: Bronsted-Lowry theory
Explanation: Bronsted-Lowry theory — verified fact for BITSAT Chemistry.
7. What is the basicity (denticity considerations aside) of ethylenediamine (en) as a ligand?
- A. Bidentate (binds through two nitrogen atoms)
- B. Monodentate
- C. Tridentate
- D. Hexadentate
Answer: Bidentate (binds through two nitrogen atoms)
Explanation: Bidentate (binds through two nitrogen atoms) — verified fact for BITSAT Chemistry.
8. Which of the following ions is expected to be coloured due to the presence of unpaired d-electrons: Sc³⁺ or Ti³⁺?
- A. Ti³⁺ (has one unpaired 3d electron)
- B. Neither ion is coloured
- C. Sc³⁺ (has no d electrons)
- D. Both are equally coloured
Answer: Ti³⁺ (has one unpaired 3d electron)
Explanation: Ti³⁺ (has one unpaired 3d electron) — verified fact for BITSAT Chemistry.
9. Which of the following best explains why transition metals commonly show variable oxidation states?
- A. They have no valence electrons
- B. The (n-1)d and ns electrons have comparable energies and can both participate in bonding
- C. They belong only to Group 1
- D. They have completely filled d-orbitals only
Answer: The (n-1)d and ns electrons have comparable energies and can both participate in bonding
Explanation: The (n-1)d and ns electrons have comparable energies and can both participate in bonding — verified fact for BITSAT Chemistry.
10. What is the geometry of the [Ni(CO)₄] complex, given its sp³ hybridisation?
- A. Octahedral
- B. Square planar
- C. Linear
- D. Tetrahedral
Answer: Tetrahedral
Explanation: Tetrahedral — verified fact for BITSAT Chemistry.
11. For the equilibrium PCl₅(g) ⇌ PCl₃(g) + Cl₂(g), what is the effect of decreasing the volume of the container (increasing pressure) on the equilibrium?
- A. Equilibrium shifts backward, favouring PCl₅ (fewer gas moles)
- B. Equilibrium shifts forward, favouring PCl₃ and Cl₂
- C. No effect on equilibrium position
- D. The reaction stops completely
Answer: Equilibrium shifts backward, favouring PCl₅ (fewer gas moles)
Explanation: Equilibrium shifts backward, favouring PCl₅ (fewer gas moles) — verified fact for BITSAT Chemistry.
12. Which of the following statements about catalysts is correct?
- A. A catalyst is completely consumed during the reaction
- B. A catalyst shifts the equilibrium position toward products
- C. A catalyst increases the enthalpy of reactants
- D. A catalyst is not consumed in the overall reaction and does not change the equilibrium position
Answer: A catalyst is not consumed in the overall reaction and does not change the equilibrium position
Explanation: A catalyst is not consumed in the overall reaction and does not change the equilibrium position — verified fact for BITSAT Chemistry.
13. What is the pOH of a solution with pH = 9 at 25°C (using pH + pOH = 14)?
- A. 4.5
- B. 5
- C. 14
- D. 9
Answer: 5
Explanation: 5 — verified fact for BITSAT Chemistry.
14. Which of the following best describes an isothermal process?
- A. A process where no heat is exchanged with surroundings
- B. A process that occurs at constant temperature
- C. A process that occurs at constant volume
- D. A process that occurs at constant pressure
Answer: A process that occurs at constant temperature
Explanation: A process that occurs at constant temperature — verified fact for BITSAT Chemistry.
15. For the first-order decomposition of a substance, if the initial concentration is 0.8 M and after one half-life the concentration becomes 0.4 M, what will the concentration be after two half-lives?
- A. 0.3 M
- B. 0.2 M
- C. 0.1 M
- D. 0.4 M
Answer: 0.2 M
Explanation: 0.2 M — verified fact for BITSAT Chemistry.
16. What is the molarity of a solution containing 4 g of NaOH (molar mass 40 g/mol) dissolved in 500 mL of solution?
- A. 0.2 M
- B. 2 M
- C. 0.1 M
- D. 0.4 M
Answer: 0.2 M
Explanation: 0.2 M — verified fact for BITSAT Chemistry.
17. Natural rubber is a polymer of which monomer unit?
- A. Ethylene
- B. Vinyl chloride
- C. Isoprene (2-methylbuta-1,3-diene)
- D. Styrene
Answer: Isoprene (2-methylbuta-1,3-diene)
Explanation: Isoprene (2-methylbuta-1,3-diene) — verified fact for BITSAT Chemistry.
18. Which type of polymerisation involves monomers joining together with the loss of a small molecule such as water?
- A. Condensation polymerisation
- B. Chain polymerisation only, without any byproduct
- C. Free radical addition polymerisation only
- D. Addition polymerisation
Answer: Condensation polymerisation
Explanation: Condensation polymerisation — verified fact for BITSAT Chemistry.
19. Nylon-6,6 is an example of which class of polymer, based on the type of linkage joining its monomer units?
- A. Elastomer formed by addition polymerisation only
- B. Condensation polymer (formed via amide linkages)
- C. Addition polymer
- D. Natural polymer
Answer: Condensation polymer (formed via amide linkages)
Explanation: Condensation polymer (formed via amide linkages) — verified fact for BITSAT Chemistry.
20. Polythene (polyethylene) is formed by the polymerisation of which monomer?
- A. Vinyl chloride
- B. Ethylene (ethene, CH₂=CH₂)
- C. Propylene (propene)
- D. Styrene
Answer: Ethylene (ethene, CH₂=CH₂)
Explanation: Ethylene (ethene, CH₂=CH₂) — verified fact for BITSAT Chemistry.
21. Toluene undergoes electrophilic substitution faster than benzene because the methyl group is a(n):
- A. Strongly electron-withdrawing group
- B. Deactivating, meta-directing group
- C. Activating, ortho/para-directing group (electron-donating by hyperconjugation)
- D. Non-directing, inert group
Answer: Activating, ortho/para-directing group (electron-donating by hyperconjugation)
Explanation: Activating, ortho/para-directing group (electron-donating by hyperconjugation) — verified fact for BITSAT Chemistry.
22. In the nitration of benzene, which electrophile attacks the benzene ring?
- A. Nitrate ion (NO₃⁻)
- B. Ammonium ion (NH₄⁺)
- C. Nitronium ion (NO₂⁺)
- D. Nitrogen dioxide radical (NO₂•)
Answer: Nitronium ion (NO₂⁺)
Explanation: Nitronium ion (NO₂⁺) — verified fact for BITSAT Chemistry.
23. According to Huckel's rule, a planar cyclic molecule is aromatic if it has how many delocalised pi electrons (for the smallest case)?
- A. 10
- B. 6 (following the 4n+2 rule with n = 1)
- C. 4
- D. 8
Answer: 6 (following the 4n+2 rule with n = 1)
Explanation: 6 (following the 4n+2 rule with n = 1) — verified fact for BITSAT Chemistry.
24. Which of the following reactions is characteristic of benzene due to its aromatic stability: electrophilic substitution or electrophilic addition?
- A. Electrophilic substitution
- B. Electrophilic addition
- C. Free radical addition
- D. Nucleophilic substitution
Answer: Electrophilic substitution
Explanation: Electrophilic substitution — verified fact for BITSAT Chemistry.
25. What is the molecular formula of benzene?
- A. C₅H₅
- B. C₆H₁₄
- C. C₆H₆
- D. C₆H₁₂
Answer: C₆H₆
Explanation: C₆H₆ — verified fact for BITSAT Chemistry.
26. Which functional group is present in both aldehydes and ketones, distinguishing them as carbonyl compounds?
- A. C=O (carbonyl group)
- B. -OH (hydroxyl group)
- C. -COOH (carboxyl group)
- D. -NH₂ (amine group)
Answer: C=O (carbonyl group)
Explanation: C=O (carbonyl group) — verified fact for BITSAT Chemistry.
27. Carboxylic acids are generally more acidic than alcohols mainly because of:
- A. A larger molecular size
- B. A lower boiling point
- C. Resonance stabilisation of the carboxylate anion formed after deprotonation
- D. The presence of more hydrogen atoms
Answer: Resonance stabilisation of the carboxylate anion formed after deprotonation
Explanation: Resonance stabilisation of the carboxylate anion formed after deprotonation — verified fact for BITSAT Chemistry.
28. Primary alcohols on oxidation with a mild oxidising agent like PCC typically form which functional group first?
- A. Ketone
- B. Carboxylic acid directly
- C. Ether
- D. Aldehyde
Answer: Aldehyde
Explanation: Aldehyde — verified fact for BITSAT Chemistry.
29. Which class of organic compounds is generally more basic due to the lone pair of electrons on nitrogen: amines or amides?
- A. Both are equally basic
- B. Amines
- C. Amides
- D. Neither is basic
Answer: Amines
Explanation: Amines — verified fact for BITSAT Chemistry.
30. Carboxylic acids react with alcohols in the presence of an acid catalyst to form which class of compound (esterification)?
- A. Aldehydes
- B. Amides
- C. Esters
- D. Ethers
Answer: Esters
Explanation: Esters — verified fact for BITSAT Chemistry.
31. Which of the following reagents is commonly used to distinguish aldehydes from ketones (Tollens' test)?
- A. Ammoniacal silver nitrate (Tollens' reagent), which aldehydes reduce to form a silver mirror
- B. Sodium chloride solution
- C. Dilute sulphuric acid only
- D. Sodium hydroxide alone
Answer: Ammoniacal silver nitrate (Tollens' reagent), which aldehydes reduce to form a silver mirror
Explanation: Ammoniacal silver nitrate (Tollens' reagent), which aldehydes reduce to form a silver mirror — verified fact for BITSAT Chemistry.
32. Which functional group is characteristic of alcohols?
- A. -COOH (carboxyl group)
- B. -CHO (aldehyde group)
- C. -NH₂ (amine group)
- D. -OH (hydroxyl group)
Answer: -OH (hydroxyl group)
Explanation: -OH (hydroxyl group) — verified fact for BITSAT Chemistry.
33. A homolytic bond cleavage produces which type of reactive intermediate?
- A. Carbanions
- B. Carbocations
- C. Zwitterions
- D. Free radicals
Answer: Free radicals
Explanation: Free radicals — verified fact for BITSAT Chemistry.
34. In an E2 elimination reaction, what is generally removed from adjacent carbon atoms to form a double bond?
- A. A hydrogen atom and a leaving group (anti-periplanar elimination)
- B. Two leaving groups only
- C. Two hydrogen atoms only
- D. A carbon atom itself
Answer: A hydrogen atom and a leaving group (anti-periplanar elimination)
Explanation: A hydrogen atom and a leaving group (anti-periplanar elimination) — verified fact for BITSAT Chemistry.
35. Tertiary alkyl halides generally favour which substitution mechanism over the other, due to the stability of the intermediate formed?
- A. E2 elimination is always exclusively favoured instead
- B. Neither mechanism is favoured
- C. SN1 (favoured due to a more stable tertiary carbocation)
- D. SN2 (favoured due to less steric hindrance)
Answer: SN1 (favoured due to a more stable tertiary carbocation)
Explanation: SN1 (favoured due to a more stable tertiary carbocation) — verified fact for BITSAT Chemistry.
36. An SN2 reaction mechanism is characterised by which of the following?
- A. No dependence on the nature of the leaving group
- B. Formation of a stable carbocation intermediate
- C. A single concerted step with backside attack, causing inversion of configuration
- D. Two separate steps with a carbanion intermediate
Answer: A single concerted step with backside attack, causing inversion of configuration
Explanation: A single concerted step with backside attack, causing inversion of configuration — verified fact for BITSAT Chemistry.
37. An SN1 reaction mechanism proceeds through which type of intermediate?
- A. A carbanion intermediate
- B. A carbocation intermediate
- C. No intermediate; it is a single concerted step
- D. A free radical intermediate
Answer: A carbocation intermediate
Explanation: A carbocation intermediate — verified fact for BITSAT Chemistry.
38. 1-propanol and 2-propanol differ in the position of the -OH group on the carbon chain. What type of isomerism is this?
- A. Position isomerism
- B. Metamerism
- C. Chain isomerism
- D. Functional group isomerism
Answer: Position isomerism
Explanation: Position isomerism — verified fact for BITSAT Chemistry.
39. What is the relationship between two enantiomers of a chiral molecule?
- A. They are identical in all physical and chemical properties including optical rotation direction
- B. They have different molecular formulas
- C. They differ in the position of a functional group
- D. They are non-superimposable mirror images of each other
Answer: They are non-superimposable mirror images of each other
Explanation: They are non-superimposable mirror images of each other — verified fact for BITSAT Chemistry.
40. A carbon atom bonded to four different groups is called a chiral centre. Molecules containing such a centre typically exhibit which type of isomerism?
- A. Chain isomerism
- B. Optical isomerism
- C. Ring-chain isomerism
- D. Geometrical isomerism
Answer: Optical isomerism
Explanation: Optical isomerism — verified fact for BITSAT Chemistry.
41. Cis-2-butene and trans-2-butene are examples of which type of isomerism?
- A. Chain isomerism
- B. Geometrical (cis-trans) isomerism
- C. Tautomerism
- D. Optical isomerism
Answer: Geometrical (cis-trans) isomerism
Explanation: Geometrical (cis-trans) isomerism — verified fact for BITSAT Chemistry.
42. Ethanol (CH₃CH₂OH) and dimethyl ether (CH₃OCH₃) have the same molecular formula but different structures. What type of isomerism is this?
- A. Metamerism
- B. Position isomerism
- C. Functional group isomerism
- D. Chain isomerism
Answer: Functional group isomerism
Explanation: Functional group isomerism — verified fact for BITSAT Chemistry.
43. Butane (C₄H₁₀) and isobutane are examples of which type of isomerism?
- A. Position isomerism
- B. Chain (skeletal) isomerism
- C. Functional group isomerism
- D. Geometrical isomerism
Answer: Chain (skeletal) isomerism
Explanation: Chain (skeletal) isomerism — verified fact for BITSAT Chemistry.
44. What is the IUPAC name of the compound (CH₃)₃C-OH?
- A. 2-Methylpropan-1-ol
- B. Butan-1-ol
- C. 2,2-Dimethylethanol
- D. 2-Methylpropan-2-ol
Answer: 2-Methylpropan-2-ol
Explanation: 2-Methylpropan-2-ol — verified fact for BITSAT Chemistry.
45. What is the IUPAC name of the compound CH₃-CH₂-CH₂-CHO?
- A. Butanol
- B. Butanone
- C. Butanoic acid
- D. Butanal
Answer: Butanal
Explanation: Butanal — verified fact for BITSAT Chemistry.
46. What is the IUPAC name of CH₂=CH-CH₃?
- A. Propanol
- B. Propyne
- C. Propane
- D. Propene
Answer: Propene
Explanation: Propene — verified fact for BITSAT Chemistry.
47. What is the IUPAC name of CH₃-CH₂-OH?
- A. Ethanal
- B. Ethanoic acid
- C. Methanol
- D. Ethanol
Answer: Ethanol
Explanation: Ethanol — verified fact for BITSAT Chemistry.
48. What is the IUPAC name of CH₃-CH₂-COOH?
- A. Ethanoic acid
- B. Propanoic acid
- C. Propanal
- D. Propan-1-ol
Answer: Propanoic acid
Explanation: Propanoic acid — verified fact for BITSAT Chemistry.
49. What is the IUPAC name of CH₃-CO-CH₃?
- A. Propan-1-ol
- B. Propan-2-one (acetone)
- C. Propanal
- D. Propanoic acid
Answer: Propan-2-one (acetone)
Explanation: Propan-2-one (acetone) — verified fact for BITSAT Chemistry.
50. What is the IUPAC name of the compound CH₃-CH(CH₃)-CH₂-CH₃?
- A. 2-Methylbutane
- B. 2-Methylpropane
- C. Pentane
- D. 3-Methylbutane
Answer: 2-Methylbutane
Explanation: 2-Methylbutane — verified fact for BITSAT Chemistry.
51. To balance the half-reaction Fe²⁺ → Fe³⁺ + e⁻, this reaction represents:
- A. Reduction (gain of an electron)
- B. Neutralisation
- C. Disproportionation
- D. Oxidation (loss of an electron)
Answer: Oxidation (loss of an electron)
Explanation: Oxidation (loss of an electron) — verified fact for BITSAT Chemistry.
52. What is the oxidation state of chromium in the dichromate ion, Cr₂O₇²⁻?
- A. +7
- B. +2
- C. +6
- D. +3
Answer: +6
Explanation: +6 — verified fact for BITSAT Chemistry.
53. In a redox reaction, the substance that gains electrons is called the:
- A. Catalyst
- B. Reducing agent
- C. Oxidising agent
- D. Buffer
Answer: Oxidising agent
Explanation: Oxidising agent — verified fact for BITSAT Chemistry.
54. In the compound KMnO₄, manganese exhibits which oxidation state?
- A. +7
- B. +2
- C. +4
- D. +6
Answer: +7
Explanation: +7 — verified fact for BITSAT Chemistry.
55. In the reaction Zn + CuSO₄ → ZnSO₄ + Cu, which species is oxidised?
- A. Cu (copper metal)
- B. Zn (zinc)
- C. Cu²⁺ (copper ion)
- D. SO₄²⁻ (sulphate ion)
Answer: Zn (zinc)
Explanation: Zn (zinc) — verified fact for BITSAT Chemistry.
56. What is the conjugate base of the acid H₂SO₄ after it donates one proton?
- A. SO₃²⁻
- B. SO₄²⁻
- C. HSO₄⁻
- D. H₃SO₄⁺
Answer: HSO₄⁻
Explanation: HSO₄⁻ — verified fact for BITSAT Chemistry.
57. BF₃ acts as a Lewis acid because it:
- A. Has a lone pair of electrons to donate
- B. Readily donates a proton
- C. Has a complete octet and is chemically inert
- D. Has an incomplete octet on boron and can accept an electron pair
Answer: Has an incomplete octet on boron and can accept an electron pair
Explanation: Has an incomplete octet on boron and can accept an electron pair — verified fact for BITSAT Chemistry.
58. At 25°C, a chemically neutral aqueous solution has a pH value of:
- A. 1
- B. 0
- C. 7
- D. 14
Answer: 7
Explanation: 7 — verified fact for BITSAT Chemistry.
59. What is the pH of a 0.01 M HCl solution, assuming complete dissociation?
- A. 7
- B. 2
- C. 1
- D. 12
Answer: 2
Explanation: 2 — verified fact for BITSAT Chemistry.
60. According to the Lewis theory, a Lewis base is defined as a species that:
- A. Donates an electron pair
- B. Donates a proton
- C. Accepts a proton
- D. Accepts an electron pair
Answer: Donates an electron pair
Explanation: Donates an electron pair — verified fact for BITSAT Chemistry.
61. According to the Bronsted-Lowry theory, an acid is defined as a substance that:
- A. Donates an electron pair
- B. Accepts a hydroxide ion
- C. Donates a proton (H⁺)
- D. Accepts a proton (H⁺)
Answer: Donates a proton (H⁺)
Explanation: Donates a proton (H⁺) — verified fact for BITSAT Chemistry.
62. In coordination chemistry, a ligand that can bind to a metal ion through two donor atoms simultaneously is called:
- A. Ambidentate ligand only
- B. Non-coordinating ligand
- C. Monodentate ligand
- D. Bidentate ligand
Answer: Bidentate ligand
Explanation: Bidentate ligand — verified fact for BITSAT Chemistry.
63. A complex is diamagnetic if all its electrons in the d-orbitals are:
- A. In an excited state
- B. Unpaired
- C. Removed entirely
- D. Paired
Answer: Paired
Explanation: Paired — verified fact for BITSAT Chemistry.
64. What is the IUPAC name of the complex [Cu(NH₃)₄]SO₄?
- A. Tetraamminecopper(I) sulphate
- B. Ammine copper sulphate
- C. Copper tetraammine sulphate(IV)
- D. Tetraamminecopper(II) sulphate
Answer: Tetraamminecopper(II) sulphate
Explanation: Tetraamminecopper(II) sulphate — verified fact for BITSAT Chemistry.
65. According to Werner's theory, what is the term for the number of ligand donor atoms directly bonded to the central metal ion?
- A. Primary valency only
- B. Oxidation number
- C. Coordination number
- D. Denticity of the complex
Answer: Coordination number
Explanation: Coordination number — verified fact for BITSAT Chemistry.
66. What is the oxidation state of cobalt in the complex [Co(NH₃)₆]Cl₃?
- A. 0
- B. +3
- C. +6
- D. +2
Answer: +3
Explanation: +3 — verified fact for BITSAT Chemistry.
67. What is the coordination number of the central metal ion in the complex [Co(NH₃)₆]³⁺?
- A. 4
- B. 3
- C. 2
- D. 6
Answer: 6
Explanation: 6 — verified fact for BITSAT Chemistry.
68. Which of these s-block elements imparts a characteristic brick-red colour to a flame test?
- A. Lithium
- B. Potassium
- C. Calcium
- D. Sodium
Answer: Calcium
Explanation: Calcium — verified fact for BITSAT Chemistry.
69. Which element is called the 'metalloid' that is widely used as a semiconductor in the electronics industry?
- A. Carbon
- B. Silicon
- C. Sulphur
- D. Phosphorus
Answer: Silicon
Explanation: Silicon — verified fact for BITSAT Chemistry.
70. Which halogen exists as a liquid at room temperature?
- A. Chlorine
- B. Bromine
- C. Fluorine
- D. Iodine
Answer: Bromine
Explanation: Bromine — verified fact for BITSAT Chemistry.
71. Which noble gas is used in balloons and airships due to its low density and inertness?
- A. Neon
- B. Xenon
- C. Helium
- D. Argon
Answer: Helium
Explanation: Helium — verified fact for BITSAT Chemistry.
72. Which of the following is the most common oxidation state shown by alkaline earth metals (Group 2) in their compounds?
- A. +3
- B. +1
- C. +2
- D. -2
Answer: +2
Explanation: +2 — verified fact for BITSAT Chemistry.
73. Which group of the periodic table is known as the alkali metals?
- A. Group 2
- B. Group 17
- C. Group 1
- D. Group 18
Answer: Group 1
Explanation: Group 1 — verified fact for BITSAT Chemistry.
74. Which of these has the highest second ionisation energy considering the noble gas configuration reached after removing one electron: Na or Mg?
- A. Neither has a defined second ionisation energy
- B. Na (removing a second electron breaks a stable noble-gas-like Ne configuration)
- C. Mg
- D. Both are equal
Answer: Na (removing a second electron breaks a stable noble-gas-like Ne configuration)
Explanation: Na (removing a second electron breaks a stable noble-gas-like Ne configuration) — verified fact for BITSAT Chemistry.
75. Why is the ionic radius of a cation always smaller than the atomic radius of its parent atom?
- A. Because removing electrons reduces electron-electron repulsion and effective nuclear attraction increases per electron
- B. Because the atomic mass decreases significantly
- C. Because protons are lost along with electrons
- D. Because the nucleus shrinks when electrons are removed
Answer: Because removing electrons reduces electron-electron repulsion and effective nuclear attraction increases per electron
Explanation: Because removing electrons reduces electron-electron repulsion and effective nuclear attraction increases per electron — verified fact for BITSAT Chemistry.
76. Which of these elements has the highest electronegativity: F, Cl, Br, I?
- A. Cl
- B. I
- C. F
- D. Br
Answer: F
Explanation: F — verified fact for BITSAT Chemistry.
77. How does ionisation energy generally change on moving down a group in the periodic table?
- A. It generally decreases
- B. It generally increases
- C. It remains constant
- D. It becomes negative
Answer: It generally decreases
Explanation: It generally decreases — verified fact for BITSAT Chemistry.
78. How does atomic radius generally change on moving from left to right across a period?
- A. It generally increases
- B. It remains constant
- C. It first increases then decreases
- D. It generally decreases
Answer: It generally decreases
Explanation: It generally decreases — verified fact for BITSAT Chemistry.
79. What is the van't Hoff factor (i) for a solute like NaCl that undergoes complete dissociation into 2 ions in dilute aqueous solution?
- A. 2
- B. 0.5
- C. 4
- D. 1
Answer: 2
Explanation: 2 — verified fact for BITSAT Chemistry.
80. Adding a non-volatile solute to a pure solvent causes the boiling point of the solution to:
- A. Increase (elevation in boiling point)
- B. Become equal to the freezing point
- C. Remain unchanged
- D. Decrease
Answer: Increase (elevation in boiling point)
Explanation: Increase (elevation in boiling point) — verified fact for BITSAT Chemistry.